Both teams have underwhelmed in the competition so far this season, with Bayern picking up six points from four matches to sit down in 17th spot in the Champions League table, while PSG are 25th, having only managed to secure four points from their four games.
Bayern - top of the Bundesliga table - will enter the contest off the back of a 3-0 victory over Augsburg on Friday night, while PSG were also 3-0 winners over Toulouse last time out to move six points clear at the top of the Ligue 1 table.
Here, Sports Mole takes an in-depth look at the head-to-head record and previous meetings between the two sides ahead of what is shaping up to be a fascinating clash in Munich.
Head-to-head record
Previous meetings: 13
Bayern wins: 7
Draws: 0
PSG wins: 6
Bayern and PSG have locked horns on 13 occasions throughout history, and there has not been a single draw, with Bayern just leading the head-to-head seven wins to six, and the pair have faced off regularly in recent years.
Bayern are actually on a three-game winning run against PSG, including 1-0 and 2-0 victories when the pair faced off in the last-16 stage of the 2022-23 Champions League.
The Munich giants also beat PSG 1-0 in the second leg of their contest in the quarter-finals of the 2020-21 competition, although the French outfit progressed to the final four on the away-goals rule.
The most famous meeting between the two sides came in the Champions League final in August 2020, though, and it was Bayern that emerged victorious courtesy of a 59th-minute header from Kingsley Coman.
Bayern have won five of the last six meetings between the two sides, but their early contests were dominated by PSG.
The opening eight games between Bayern and PSG took place in the group stage of the Champions League, and the French outfit posted five wins, including a 1-0 success in Munich back in November 1994.
PSG have two away victories over Bayern to their name, and they will be bidding to end a three-game losing streak against the Bundesliga side when the two teams lock horns at Allianz Arena on Tuesday night.
Bayern have actually won 12 of their last 14 games against French sides home and away, while PSG have been beaten in eight of their 15 away matches against German clubs in the competition's history.
Previous meetings
Mar 08, 2023: Bayern 2-0 PSG (Champions League Round of 16)
Feb 14, 2023: PSG 0-1 Bayern (Champions League Round of 16)
Apr 13, 2021: PSG 0-1 Bayern (Champions League Quarter-Finals)
Apr 07, 2021: Bayern 2-3 PSG (Champions League Quarter-Finals)
Aug 23, 2020: PSG 0-1 Bayern (Champions League Final)
Dec 05, 2017: Bayern 3-1 PSG (Champions League Group Stage)
Sep 27, 2017: PSG 3-0 Bayern (Champions League Group Stage)
Oct 18, 2000: Bayern 2-0 PSG (Champions League Group Stage)
Sep 26, 2000: PSG 1-0 Bayern (Champions League Group Stage)
Nov 05, 1997: PSG 3-1 Bayern (Champions League Group Stage)
Oct 22, 1997: Bayern 5-1 PSG (Champions League Group Stage)
Nov 23, 1994: Bayern 0-1 PSG (Champions League Group Stage)
Sept 14, 1994: PSG 2-0 Bayern (Champions League Group Stage)