Both nations got off the mark at the second attempt last time out, as Serhiy Rebrov's side fought back from a goal down to sink Slovakia 2-1, while the Red Devils were 2-0 victors against Romania.
Match preview
Anything and everything is still possible on the final matchday of Euro 2024 Group E, in which all four sides boast three points from their opening two fixtures - an all-time first at the Championships - but the Ukrainians currently reside at the bottom of the pile on account of their inferior goal difference.
After shipping three to the Romanians - a dreadful affair which saw Real Madrid's Andriy Lunin lose his place in goal for matchday two - Ukraine were on the verge of seeing their Euros adventure come to a premature end when Ivan Schranz netted for the second time in two games for Slovakia.
However, Mykola Shaparenko's calm finish from Oleksandr Zinchenko's cross brought Ukraine level, and even though Roman Yaremchuk wasted one golden opportunity with an over-hit pass to Mykhaylo Mudryk, he more than made up for it in the 80th minute with an exquisite touch and finish to complete the turnaround.
Still in with a shot of last-16 qualification thanks to their dramatic fightback, the formula is simple for the Blue and Yellow, who will guarantee a top-two ranking if they win and could even finish first in the section with all three points if they better Romania's result.
Alternatively, a draw would suffice for third - and potentially a last-16 path - if there is a winner in Romania's clash with Slovakia, and even defeat may not prove fatal if the latter team also suffer defeat, but Rebrov's men will not concern themselves with such complicated number-crunching here.
However hard he may try, the ball just will not go into the back of the net for Belgium's all-time top scorer Romelu Lukaku at Euro 2024, and while his blushes were not spared in the Red Devils' shock opening loss to Slovakia, but it was a different story on Saturday.
A crisp 73rd-second strike from Youri Tielemans - the quickest goal that the Belgian men's team have ever scored at a major tournament - set Domenico Tedesco's men on the path to victory versus Romania, before a Koen Casteels punt forward went all the way through for Kevin De Bruyne to slot home number two.
There were sighs of relief all around as De Bruyne rubber-stamped Belgium's pivotal success in Cologne, one which currently has the Red Devils second in the section and safe in the knowledge that they only need to avoid defeat on Wednesday to guarantee a knockout place.
First place will be theirs if they triumph and Slovakia only manage a draw or defeat to Romania, but a loss coupled with Romania obtaining at least one point will condemn them to another dismal group-stage exit following such a fate at the 2022 World Cup.
With the shock loss to Slovakia representing their only reverse from their last 17 matches across all competitions, Tedesco's men ought to be optimistic of avoiding a repeat of their Qatar heartache on Wednesday, where they will remarkably meet Ukraine in a senior men's international for the very first time.
Ukraine European Championship form:
L
W
Ukraine form (all competitions):
W
D
L
W
L
W
Belgium European Championship form:
L
W
Belgium form (all competitions):
D
D
W
W
L
W
Team News
As Vitaliy Mykolenko was given the green light to make the matchday squad in the triumph over Slovakia, all of Ukraine's players are fit and raring to go for Wednesday's crunch affair, although the Everton left-back did not earn any minutes on matchday two.
Yaremchuk and right-back Yukhym Konoplya will both sit out any potential last-16 tie if they pick up yellow cards in Stuttgart, but the former should lose out to Artem Dovbyk for the number nine spot anyway, despite his Euros-saving contribution last time out.
Anatoliy Trubin more than justified his selection over Lunin in between the posts for the triumph over Slovakia and should get the nod in goal again here, while Zinchenko may revert to his usual midfield role for his country if Mykolenko is deemed OK to start.
Regarding Belgium's injury situation, neither Axel Witsel (adductor) nor Thomas Meunier (thigh) were fit to take part in the win over Romania and remain doubtful for Wednesday's showdown too, where Dodi Lukebakio must serve a suspension.
Lukebakio's ban opens the door for either Leandro Trossard or Johan Bakayoko to return to the final third, while Rennes defender Arthur Theate played down concerns over his fitness after he was forced off in the 77th minute with a blow to the thigh.
Theate should therefore be given the all-clear to reprise his role in defence, and the same can be said for 37-year-old Jan Vertonghen, who is now the third-oldest man to play for Belgium at a major tournament behind Pierre Braine and Wilfried Van Moer.
Ukraine possible starting lineup:
Trubin; Tymchyk, Zabarnyi, Matvienko, Mykolenko; Sudakov, Zinchenko, Shaparenko; Yarmolenko, Dovbyk, Mudryk
Belgium possible starting lineup:
Casteels; Castagne, Faes, Vertonghen, Theate; Tielemans, Onana; Doku, De Bruyne, Trossard; Lukaku
We say: Ukraine 1-2 Belgium
The volume of chances created is never a problem for Belgium, who have instead been guilty of spurning chance after chance in their opening two games so far, although such profligacy did not cost them against Romania.