The Gunners sit top of the rankings with nine points from nine, while Ruud van Nistelrooy's men are two worse off than their hosts in second, and here Sports Mole rounds up the team news for both clubs.
ARSENAL vs. PSV EINDHOVEN
ARSENAL
Out: Mohamed Elneny (hamstring), Emile Smith Rowe (groin)
Doubtful: Oleksandr Zinchenko (calf), Gabriel Martinelli (illness)
Sports Mole's predicted XI: Turner; White, Holding, Gabriel, Tierney; Xhaka, Partey; Saka, Vieira, Nelson; Nketiah
PSV EINDHOVEN
Out: Yorbe Vertessen (muscle), Ismael Saibari (hamstring), Olivier Boscagli (knee), Marco van Ginkel (hamstring)
Doubtful: Noni Madueke (ankle), Luuk de Jong (calf), Mauro Junior (groin)
Sports Mole's predicted XI: Benitez; Mwene, Ramalho, Obispo, Max; Sangare, Gutierrez; Simons, Veerman, Gakpo; Til
For data analysis of the most likely results, scorelines and more for this match please click here.