The Lionesses will look to return to winning ways having lost two of their last three matches - more than in their previous 38 games under Sarina Wiegman.
Crucially, one of those was the 2023 Women's World Cup final, with England suffering a tournament hangover in the Nations League.
England fell to a 2-1 defeat to the Netherlands last time out but have a chance to take control of Group A with a victory.
The European champions have won their last two games against Belgium under Wiegman and haven't lost a competitive international on home soil since 2005.
England vs Belgium: talkSPORT coverage
This Women's Nations League clash will take place on Friday, October 27.
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Kick-off at the King Power Stadium is scheduled for 7:45pm.
talkSPORT 2 will have live coverage from Leicester City's home stadium, with Faye Carruthers as your presenter.
Commentary comes from Joe Shennan and former Sheffield United Women's striker Courtney Sweetman-Kirk.
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England vs Belgium: Team news and squad
Beth Mead was a major absentee from the latest squad despite making her return from an ACL injury to Arsenal.
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However, former England star Izzy Christiansen told talkSPORT that she believes Wiegman is right to be patient with Mead.
Fran Kirby and Keira Walsh have both returned from injury while Grace Clinton and goalkeeper Khiara Keating have received their first call-ups.
England Squad
Goalkeepers: Mary Earps (Manchester United), Hannah Hampton (Chelsea), Khiara Keating (Manchester City), Ellie Roebuck (Manchester City)
Defenders: Millie Bright (Chelsea), Lucy Bronze (Barcelona), Jess Carter (Chelsea), Niamh Charles (Chelsea), Alex Greenwood (Manchester City), Maya Le Tissier (Manchester United), Esme Morgan (Manchester City), Lucy Parker (Aston Villa), Lotte Wubben-Moy (Arsenal)
Midfielders: Grace Clinton (Tottenham Hotspur, loan from Manchester United),Fran Kirby (Chelsea), Georgia Stanway (Bayern Munich), Ella Toone (Manchester United), Keira Walsh (Barcelona), Katie Zelem (Manchester United)
Forwards: Rachel Daly (Aston Villa), Lauren Hemp (Manchester City), Lauren James (Chelsea), Chloe Kelly (Manchester City), Jess Park (Manchester City), Alessia Russo (Arsenal)
England vs Belgium: What has been said?
Wiegman said: "It's good for us to be back together.
"Obviously we had a good start with the win against Scotland; however, the outcome of our last fixture against the Netherlands was disappointing.
"We will be fully focused to perform well twice against tough opposition. Belgium's results in the Nations League show they are talented side who can cause teams problems, so we will need to be at our best to get the results we're looking for.
"The group is wide open, so every game is crucial. The squad have shown their ability to respond to setbacks and I'm sure this will be no different.
"We look forward to meeting up at St George's Park next Monday and putting in the time to make sure we're fully prepared and ready to go twice in quick succession.
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"Again we feel very fortunate to be playing in front of a sell-out crowd. The support we are receiving from all corners of the country is amazing, it isn't something we'll ever take for granted and it really gives us that extra lift.
"Hopefully we can give them another night to remember."