Hansi Flick's side are currently top of the table, boasting 21 points from their opening eight matches, while Alaves occupy 11th, and here Sports Mole rounds up the team news for the two sides.
ALAVES vs. BARCELONA
ALAVES
Out: None
Doubtful: Hugo Novoa (muscle)
Sports Mole's predicted XI: Sivera; Tenaglia, Abqar, Sedlar, Diarra; Jordan, Benavidez; Vicente, Stoichkov, Martin; T Martinez
BARCELONA
Out: Marc-Andre ter Stegen (knee), Fermin Lopez (leg), Dani Olmo (hamstring), Marc Bernal (knee), Andreas Christensen (Achilles), Ronald Araujo (hamstring), Gavi (knee)
Doubtful: Inigo Martinez (muscle)
Sports Mole's predicted XI: Pena; Kounde, Cubarsi, I Martinez, Balde; Casado, E Garcia, Pedri; Yamal, Lewandowski, Raphinha
For data analysis of the most likely results, scorelines and more for this match please click here.